A.c(H2SO4)= 98g 98g/mol 1L =1mol/L;B.c(H2SO4)= 49g 98g/mol 0.5L =1mol/LC.c(H2SO4)= 98g 98g/mol 2L =0.5mol/L;D.c(H2SO4)= 24.5g 98g/mol 0.1L =2.5mol/L,则浓度最大的是D,故选D.